Charge-transfer reaction (in mass spectrometry)

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IUPAC RECOMMENDATIONS 2013

K. K. Murray, R. K. Boyd, M. N. Eberlin, G. J. Langley, L. Li and Y. Naito, Pure Appl. Chem., 2013, 85, 1515-1609, 10.1351/PAC-REC-06-04-06.

Charge-transfer reaction (in mass spectrometry)
Charge-transfer reaction (in mass spectrometry)

charge exchange reaction

Reaction of an ion with a neutral or collision partner ion in which some or all of the charge on the reactant ion is transferred to the neutral or collision partner ion.

Related Term(s):
Reference(s):

Revised from IUPAC. Analytical Division. Compendium of Analytical Nomenclature (the “Orange Book”). Definitive Rules, 1979. Compiled by J. Inczédy, T. Lengyel, A. M. Ure. Blackwell Scientific Publications, Oxford (1997). On-line corrected version: http://www.iupac.org /publications/analytical compendium (2000).

IUPAC. Compendium of Chemical Terminology, 2nd ed. (the “Gold Book”). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins.

using additional information from

P. S. Rudolph, C. E. Melton. J. Chem. Phys. 32, 586 (1960). (http://dx.doi.org/10.1063/1.1730740 )

Definitions of Terms Relating to Mass Spectrometry (IUPAC Recommendations 2013); DOI: 10.1351/PAC-REC-06-04-06 © IUPAC 2013.


Index of Terms

 




Orange Book

ORANGE BOOK DEFINITION

IUPAC. Analytical Division. Compendium of Analytical Nomenclature (the “Orange Book”). Definitive Rules, 1979.

Charge-transfer reaction (in mass spectrometry)

An ion/neutral species reaction in which the total charge on the reactant ion is transferred initially to the reactant neutral species so that the reactant ion becomes a neutral entity. Some of the possible reactions of ions M2+, M+ and M- with a neutral species X are categorized in terms of the above definitions as follows:

M2+ + X → M+ + X+ (Partial charge transfer)

M+ + X → M2+ + X + e (Charge stripping)

M- + X → M+ + X + 2e (Charge stripping & charge inversion)

These are all ion/neutral species reactions and also charge permutation reactions.

IUPAC Orange Book Chapter 12
Index of Orange Book Terms


Gold Book

GOLD BOOK DEFINITION

IUPAC. Compendium of Chemical Terminology, 2nd ed. (the “Gold Book”). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997).

Charge-transfer reaction (in mass spectrometry)

http://goldbook.iupac.org/C01005.html

An ion/neutral species reaction wherein the total charge on the reactant ion is transferred initially to the reactant neutral species so that the reactant ion becomes a neutral entity. Considering some of the possible reactions of ions M2+, M+ and M? with a neutral species X, these would be further categorized as follows:

M2+ + X → M+ + X+ (Partial charge transfer)

M+ + X → M2+ + X + e (Charge stripping)

M- + X → M+ + X + 2e (Charge stripping & charge inversion)

All are ion/neutral species reactions and also charge permutation reactions.

Source: PAC, 1991, 63, 1541 (Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)) on page 1555

IUPAC Gold Book
Index of Gold Book Terms