Charge remote fragmentation

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IUPAC RECOMMENDATIONS 2013

K. K. Murray, R. K. Boyd, M. N. Eberlin, G. J. Langley, L. Li and Y. Naito, Pure Appl. Chem., 2013, 85, 1515-1609, 10.1351/PAC-REC-06-04-06.

Charge remote fragmentation (CRF)
Fragmentation of an ion in which the cleaved bond is isolated from the apparent charge site by a distance of several bond lengths.
Related Term(s): charge-mediated fragmentation
Reference(s):

A. Savagnac, H. Aurelle, C. Casas, F. Couderc, P. Gavard, D. Prome, J. C. Prome. Chem. Phys. Lipids 51, 31 (1989). (http://dx.doi.org/10.1016/0009-3084(89)90063-7 )

K. B. Tomer, N. J. Jensen, M. L. Gross, J. Whitney. Biomed. Environ. Mass Spectrom. 13, 265 (1986). (http://dx.doi.org/10.1002/bms.1200130602 )

Definitions of Terms Relating to Mass Spectrometry (IUPAC Recommendations 2013); DOI: 10.1351/PAC-REC-06-04-06 © IUPAC 2013.


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