Electron capture dissociation
| IUPAC RECOMMENDATIONS 2013
K. K. Murray, R. K. Boyd, M. N. Eberlin, G. J. Langley, L. Li and Y. Naito, Pure Appl. Chem., 2013, 85, 1515-1609, 10.1351/PAC-REC-06-04-06.
|Electron capture dissociation (ECD)|
|Process in which multiply protonated molecules interact with low-energy electrons followed by fragmentation. The capture of an electron by the even-electron cation [M + nH]n+ liberates energy and reduces its charge state, thus producing the corresponding [M + nH](n–1)+• odd-electron ion, which readily fragments.|
R. A. Zubarev, N. L. Kelleher, F. W. McLafferty. J. Am. Chem. Soc. 120, 3265 (1998). (http://dx.doi.org/10.1021/ja973478k )
|Definitions of Terms Relating to Mass Spectrometry (IUPAC Recommendations 2013); DOI: 10.1351/PAC-REC-06-04-06 © IUPAC 2013.|