Fragment ion

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IUPAC RECOMMENDATIONS 2013

K. K. Murray, R. K. Boyd, M. N. Eberlin, G. J. Langley, L. Li and Y. Naito, Pure Appl. Chem., 2013, 85, 1515-1609, 10.1351/PAC-REC-06-04-06.

Fragment ion
Product ion that results from the dissociation of a precursor ion.
Related Term(s):
Reference(s):

Revised from

IUPAC. Analytical Division. Compendium of Analytical Nomenclature (the “Orange Book”). Definitive Rules, 1979. Compiled by J. Inczédy, T. Lengyel, A. M. Ure. Blackwell Scientific Publications, Oxford (1997). On-line corrected version: http://www.iupac.org /publications/analytical compendium (2000).

IUPAC. Compendium of Chemical Terminology, 2nd ed. (the “Gold Book”). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins.

and from

G. Glish. J. Am. Soc. Mass Spectrom. 2, 349 (1991). (http://dx.doi.org/10.1016/1044-0305(91)80026-4 )

G. C. Thorne, K. D. Ballard, S. J. Gaskell. J. Am. Soc. Mass Spectrom. 1, 249 (1990). (http://dx.doi.org/10.1016/1044-0305(90)85042-K )

Definitions of Terms Relating to Mass Spectrometry (IUPAC Recommendations 2013); DOI: 10.1351/PAC-REC-06-04-06 © IUPAC 2013.


Index of Terms

 




Orange Book

ORANGE BOOK DEFINITION

IUPAC. Analytical Division. Compendium of Analytical Nomenclature (the “Orange Book”). Definitive Rules, 1979.

Fragment ion

An electrically charged dissociation product of an ionic fragmentation. Such an ion may dissociate further to produce other electrically charged molecular or atomic moieties of successively lower formula weight. See also Daughter ion.

IUPAC Orange Book Chapter 12
Index of Orange Book Terms


Gold Book

GOLD BOOK DEFINITION

IUPAC. Compendium of Chemical Terminology, 2nd ed. (the “Gold Book”). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997).

Fragment ion

http://goldbook.iupac.org/F02508.html

An electrically charged dissociation product of an ionic fragmentation. Such an ion may dissociate further to form other electrically charged molecular or atomic moieties of successively lower formula weight.

See also: daughter ion

Source: PAC, 1991, 63, 1541 (Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)) on page 1549

Orange Book, p. 205

PAC, 1990, 62, 2167 (Glossary of atmospheric chemistry terms (Recommendations 1990)) on page 2190

IUPAC Gold Book
Index of Gold Book Terms