Ion kinetic energy spectrum

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IUPAC RECOMMENDATIONS 2013

K. K. Murray, R. K. Boyd, M. N. Eberlin, G. J. Langley, L. Li and Y. Naito, Pure Appl. Chem., 2013, 85, 1515-1609, 10.1351/PAC-REC-06-04-06.

Ion kinetic energy spectrum (IKES)
Spectrum obtained when a beam of ions is separated according to the translational energy-to-charge ratios of the ions contained in it.
Note 1: A radial electric field (E) achieves separation of the various ionic species in this way.
Note 2: In this context, kinetic energy is interpreted as translational, rather than vibrational or rotational kinetic energy.
Related Term(s): ion energy loss spectrum, mass-analyzed ion kinetic energy spectrometry (MIKES).
Reference(s):

IUPAC. Analytical Division. Compendium of Analytical Nomenclature (the “Orange Book”). Definitive Rules, 1979. Compiled by J. Inczédy, T. Lengyel, A. M. Ure. Blackwell Scientific Publications, Oxford (1997). On-line corrected version: http://www.iupac.org /publications/analytical compendium (2000).

IUPAC. Compendium of Chemical Terminology, 2nd ed. (the “Gold Book”). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins.

Definitions of Terms Relating to Mass Spectrometry (IUPAC Recommendations 2013); DOI: 10.1351/PAC-REC-06-04-06 © IUPAC 2013.


Index of Terms

 




Orange Book

ORANGE BOOK DEFINITION

IUPAC. Analytical Division. Compendium of Analytical Nomenclature (the “Orange Book”). Definitive Rules, 1979.

Ion kinetic energy spectrum

A spectrum obtained when a beam of ions is separated according to the translational energy-to-charge ratios of the ionic species contained in it. A radial electric field (E) achieves separation of the various ionic species in this way.

IUPAC Orange Book Chapter 12
Index of Orange Book Terms


Gold Book

GOLD BOOK DEFINITION

IUPAC. Compendium of Chemical Terminology, 2nd ed. (the “Gold Book”). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997).

Ion kinetic energy spectrum

http://goldbook.iupac.org/I03218.html

A spectrum obtained when a beam of ions is separated according to the translational energy-to-charge ratios of the ionic species contained within it. A radial electric field (E) achieves separation of the various ionic species in this way.

Source: PAC, 1991, 63, 1541 (Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)) on page 1550

IUPAC Gold Book
Index of Gold Book Terms