Chemical ionization: Difference between revisions

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Describes the process whereby new ionized species are formed when gaseous molecules interact with ions. The process may involve transfer of an electron, a proton or other charged species between the reactants. When a positive ion results from chemical ionization the term may be used without qualification. When a negative ion results the term negative ion chemical ionization should be used. Note that this term is not synonymous with [[chemi-ionization]], nor with [[Negative Chemical Ionization|negative chemical ionization]].
Describes the process whereby new ionized species are formed when gaseous molecules interact with ions. The process may involve transfer of an electron, a proton or other charged species between the reactants. When a positive ion results from chemical ionization the term may be used without qualification. When a negative ion results the term negative ion chemical ionization should be used. Note that this term is not synonymous with [[chemi-ionization]], nor with [[Negative Chemical Ionization|negative chemical ionization]].
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== Gold Book entry ==
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http://goldbook.iupac.org/C01026.html
This concerns the process whereby new ionization species are formed when gaseous molecules interact with ions. The process may involve transfer of an electron, proton or other charged species between the reactants. When a positive ion results from chemical ionization, the term may be used without qualification. When a negative ion is involved, the term negative ion chemical ionization should be used; note that negative ion formation by attachment of a free electron does not fall within this definition. Chemical ionization and chemi-ionization are two terms which should not be used interchangeably.
See: electron attachment
See also: chemi-ionization
Source: PAC, 1991, 63, 1541 ([[Recommendations for nomenclature and symbolism for mass spectroscopy]] (including an appendix of terms used in vacuum technology). (Recommendations 1991)) on page 1547
Orange Book, p. 204
PAC, 1990, 62, 2167 (Glossary of atmospheric chemistry terms (Recommendations 1990)) on page 2179
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Revision as of 22:14, 15 July 2009

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Orange Book entry

Orange Book

ORANGE BOOK DEFINITION

IUPAC. Analytical Division. Compendium of Analytical Nomenclature (the Orange Book). Definitive Rules, 1979 (see also Orange Book 2023)

Chemical ionization

Describes the process whereby new ionized species are formed when gaseous molecules interact with ions. The process may involve transfer of an electron, a proton or other charged species between the reactants. When a positive ion results from chemical ionization the term may be used without qualification. When a negative ion results the term negative ion chemical ionization should be used. Note that this term is not synonymous with chemi-ionization, nor with negative chemical ionization.

IUPAC 1997 Orange Book Chapter 12
Index of Orange Book Terms


Gold Book entry

Gold Book

GOLD BOOK DEFINITION

IUPAC. Compendium of Chemical Terminology, 2nd ed. (the Gold Book). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997).

Chemical ionization

http://goldbook.iupac.org/C01026.html

This concerns the process whereby new ionization species are formed when gaseous molecules interact with ions. The process may involve transfer of an electron, proton or other charged species between the reactants. When a positive ion results from chemical ionization, the term may be used without qualification. When a negative ion is involved, the term negative ion chemical ionization should be used; note that negative ion formation by attachment of a free electron does not fall within this definition. Chemical ionization and chemi-ionization are two terms which should not be used interchangeably. See: electron attachment

See also: chemi-ionization

Source: PAC, 1991, 63, 1541 (Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)) on page 1547

Orange Book, p. 204

PAC, 1990, 62, 2167 (Glossary of atmospheric chemistry terms (Recommendations 1990)) on page 2179

IUPAC Gold Book
Index of Gold Book Terms


External links