Fast atom bombardment ionization: Difference between revisions

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{{DefName|
{{Final
This term refers to the ionization of any species by causing interaction of the sample (which may be dissolved in a solvent matrix) and a beam of neutral atoms having a high translational energy. (See also [[liquid secondary ionization]] and [[secondary ionization]].)
|acronym=([[FAB]])
}}
|def=[[Ion]]ization of molecules initiated by a beam of neutral atoms with translational energies in the keV range. Labile molecules susceptible to dissociation are dissolved in an involatile liquid matrix that absorbs the energy of the bombarding atoms to form a selvedge region above the liquid surface in which ionization of the molecules occurs.


:''Note'': Positive ions (e.g., [[protonated molecule|protonated]] or [[cationized molecule]]s) or negative ions (e.g., [[deprotonated molecule]]s) are formed depending on the polarity of ionization.
|rel=[[liquid secondary ionization]]
|ref={{obgb}}


== [[Orange Book]] Entry ==
with additional information from H. R. Morris, M. Panico, M. Barber, R. S. Bordoli, R. D. Sedgwick, A. N. Tyler. Biochem. Biophys. Res. Comm. 101, 623 (1981). (http://dx.doi.org/10.1016/0006-291X(81)91304-8 )


This term refers to the ionization of any species by causing interaction of the sample (which may be dissolved in a solvent matrix) and a beam of neutral atoms having a high translational energy. (See also [[Secondary Ionization]]).
{{psims|1000074}}


}}


== Related Terms ==
<!-- Orange Book -->
{{orange|
This term refers to the ionization of any species by causing interaction of the sample (which may be dissolved in a solvent matrix) and a beam of neutral atoms having a high translational energy. (See also [[Secondary Ionization]]).
}}


*[[SIMS]]
<!-- Gold Book -->
{{gold|
'''fast-atom bombardment (FAB) mass spectroscopy'''


http://goldbook.iupac.org/F02328.html


== External Links ==
A method in which ions are produced in a mass spectrometer from non-volatile or thermally fragile organic molecules by bombarding the compound in the condensed phase with energy-rich neutral particles.


*[http://www.asms.org/whatisms/index.html ASMS What is MS?]: [http://www.asms.org/whatisms/p11.html What Other Techniques are Used to Produce Ions?]
'''Source''':
 
PAC, 1994, 66, 1077 ([[Glossary of terms used in physical organic chemistry]] (IUPAC Recommendations 1994)) on page 1115
*[[Wikipedia:Fast atom bombardment]]
}}


[[Category:Ionization]]
[[Category:Ionization]]

Latest revision as of 22:58, 12 March 2024

IUPAC RECOMMENDATIONS 2013
Fast atom bombardment ionization (FAB)
Ionization of molecules initiated by a beam of neutral atoms with translational energies in the keV range. Labile molecules susceptible to dissociation are dissolved in an involatile liquid matrix that absorbs the energy of the bombarding atoms to form a selvedge region above the liquid surface in which ionization of the molecules occurs.
Note: Positive ions (e.g., protonated or cationized molecules) or negative ions (e.g., deprotonated molecules) are formed depending on the polarity of ionization.
Related Term(s): liquid secondary ionization
Reference(s):

IUPAC. Analytical Division. Compendium of Analytical Nomenclature (the Orange Book). Definitive Rules, 1979. Compiled by J. Inczédy, T. Lengyel, A. M. Ure. Blackwell Scientific Publications, Oxford (1997). On-line corrected version: http://www.iupac.org /publications/analytical compendium (2000).

IUPAC. Compendium of Chemical Terminology, 2nd ed. (the Gold Book). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins.

with additional information from H. R. Morris, M. Panico, M. Barber, R. S. Bordoli, R. D. Sedgwick, A. N. Tyler. Biochem. Biophys. Res. Comm. 101, 623 (1981). (http://dx.doi.org/10.1016/0006-291X(81)91304-8 )


PSI-MS: MS:1000074

From Definitions of Terms Relating to Mass Spectrometry (IUPAC Recommendations 2013); DOI: 10.1351/PAC-REC-06-04-06 © IUPAC 2013.

Index of Recommended Terms

 



Orange Book

ORANGE BOOK DEFINITION

IUPAC. Analytical Division. Compendium of Analytical Nomenclature (the Orange Book). Definitive Rules, 1979 (see also Orange Book 2023)

Fast atom bombardment ionization

This term refers to the ionization of any species by causing interaction of the sample (which may be dissolved in a solvent matrix) and a beam of neutral atoms having a high translational energy. (See also Secondary Ionization).

IUPAC 1997 Orange Book Chapter 12
Index of Orange Book Terms


Gold Book

GOLD BOOK DEFINITION

IUPAC. Compendium of Chemical Terminology, 2nd ed. (the Gold Book). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997).

Fast atom bombardment ionization

fast-atom bombardment (FAB) mass spectroscopy

http://goldbook.iupac.org/F02328.html

A method in which ions are produced in a mass spectrometer from non-volatile or thermally fragile organic molecules by bombarding the compound in the condensed phase with energy-rich neutral particles.

Source: PAC, 1994, 66, 1077 (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1115

IUPAC Gold Book
Index of Gold Book Terms
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