Fourier transform-ion cyclotron resonance-mass spectrometer: Difference between revisions
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|def=[[Mass spectrometer]] based on the principle of [[ion cyclotron resonance]] in which an [[ion]] in a magnetic field moves in a circular orbit at the cyclotron frequency that is characteristic of its ''[[m/z]]'' value. Ions are coherently excited to a larger radius orbit using a pulse of radio frequency electric field, and their image charge is detected on receiver plates as a time domain signal. Fourier transformation of the time domain signal results in a frequency domain signal that is converted to a [[mass spectrum]] based on the inverse relationship between [[cyclotron frequency]] and ''m/z''. | |||
|rel=[[ion cyclotron resonance mass spectrometer]] | |||
|ref={{obgb}} | |||
{{psims}}1000443 | |||
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<!-- Orange Book --> | |||
{{orange| | |||
A high-frequency [[mass spectrometer]] in which the [[Cyclotron Motion|cyclotron motion]] of ions, having different [[mass/charge ratio]]s, in a constant magnetic field, is excited essentially simultaneously and coherently by a pulse of a radio-frequency electric field applied perpendicularly to the magnetic field. The excited cyclotron motion of the ions is subsequently detected on [[Receiver Plate|receiver plate]]s as a time domain signal that contains all the [[Cyclotron Frequency|cyclotron frequencies]] excited. Fourier transformation of the time domain signal results in a frequency domain FT-ICR signal which, on the basis of the inverse proportionality between frequency and mass/charge ratio, can be converted to a [[mass spectrum]]. See also [[ICR|ion cyclotron resonance (ICR) mass spectrometer]]. | A high-frequency [[mass spectrometer]] in which the [[Cyclotron Motion|cyclotron motion]] of ions, having different [[mass/charge ratio]]s, in a constant magnetic field, is excited essentially simultaneously and coherently by a pulse of a radio-frequency electric field applied perpendicularly to the magnetic field. The excited cyclotron motion of the ions is subsequently detected on [[Receiver Plate|receiver plate]]s as a time domain signal that contains all the [[Cyclotron Frequency|cyclotron frequencies]] excited. Fourier transformation of the time domain signal results in a frequency domain FT-ICR signal which, on the basis of the inverse proportionality between frequency and mass/charge ratio, can be converted to a [[mass spectrum]]. See also [[ICR|ion cyclotron resonance (ICR) mass spectrometer]]. | ||
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<!-- Gold Book --> | |||
{{gold| | |||
http://goldbook.iupac.org/F02492.html | |||
A high-frequency mass spectrometer in which the cyclotron motion of ions, having different mass/charge ratios, in a constant magnetic field is excited essentially simultaneously and coherently by a pulse or a radio-frequency electric field applied perpendicular to the magnetic field. The excited cyclotron motion of the ions is subsequently detected on so-called receiver plates as a time domain signal that contains all the cyclotron frequencies that have been excited. Fourier transformation of the time domain signal results in the frequency domain FT-ICR signal which, on the basis of the inverse proportionality between frequency and the mass/charge ratio, can be converted into a mass spectrum. The term is sometimes contracted to Fourier transform mass spectrometer (FT-MS). | |||
See also: ion cyclotron resonance (ICR) mass spectrometer | |||
'''Source''': | |||
PAC, 1991, 63, 1541 ([[Recommendations for nomenclature and symbolism for mass spectroscopy]] (including an appendix of terms used in vacuum technology). (Recommendations 1991)) on page 1545 | |||
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{{psi| | |||
|def=A mass spectrometer based on the principle of ion cyclotron resonance in which an ion in a magnetic field moves in a circular orbit at a frequency characteristic of its m/z value. Ions are coherently excited to a larger radius orbit using a pulse of radio frequency energy and their image charge is detected on receiver plates as a time domain signal. Fourier transformation of the time domain signal results in a frequency domain signal which is converted to a mass spectrum based in the inverse relationship between frequency and m/z. [database_cross_reference: PSI:MS] | |||
|sup=mass analyzer type | |||
|id=MS:1000079 | |||
|anno='''has_exact_synonym:'''[[FT_ICR]] | |||
}} | |||
[[Category: | [[Category:M/z Separation]] |
Revision as of 15:23, 9 May 2016
IUPAC RECOMMENDATIONS 2013 |
Fourier transform-ion cyclotron resonance-mass spectrometer |
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Mass spectrometer based on the principle of ion cyclotron resonance in which an ion in a magnetic field moves in a circular orbit at the cyclotron frequency that is characteristic of its m/z value. Ions are coherently excited to a larger radius orbit using a pulse of radio frequency electric field, and their image charge is detected on receiver plates as a time domain signal. Fourier transformation of the time domain signal results in a frequency domain signal that is converted to a mass spectrum based on the inverse relationship between cyclotron frequency and m/z. |
Related Term(s): ion cyclotron resonance mass spectrometer |
Reference(s):
IUPAC. Analytical Division. Compendium of Analytical Nomenclature (the Orange Book). Definitive Rules, 1979. Compiled by J. Inczédy, T. Lengyel, A. M. Ure. Blackwell Scientific Publications, Oxford (1997). On-line corrected version: http://www.iupac.org /publications/analytical compendium (2000). IUPAC. Compendium of Chemical Terminology, 2nd ed. (the Gold Book). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins.
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From Definitions of Terms Relating to Mass Spectrometry (IUPAC Recommendations 2013); DOI: 10.1351/PAC-REC-06-04-06 © IUPAC 2013. |
Orange Book
ORANGE BOOK DEFINITION
IUPAC. Analytical Division. Compendium of Analytical Nomenclature (the Orange Book). Definitive Rules, 1979 (see also Orange Book 2023) |
Fourier transform-ion cyclotron resonance-mass spectrometer |
---|
A high-frequency mass spectrometer in which the cyclotron motion of ions, having different mass/charge ratios, in a constant magnetic field, is excited essentially simultaneously and coherently by a pulse of a radio-frequency electric field applied perpendicularly to the magnetic field. The excited cyclotron motion of the ions is subsequently detected on receiver plates as a time domain signal that contains all the cyclotron frequencies excited. Fourier transformation of the time domain signal results in a frequency domain FT-ICR signal which, on the basis of the inverse proportionality between frequency and mass/charge ratio, can be converted to a mass spectrum. See also ion cyclotron resonance (ICR) mass spectrometer. |
IUPAC 1997 Orange Book Chapter 12 |
Index of Orange Book Terms |
Gold Book
GOLD BOOK DEFINITION
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the Gold Book). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). |
Fourier transform-ion cyclotron resonance-mass spectrometer |
---|
http://goldbook.iupac.org/F02492.html A high-frequency mass spectrometer in which the cyclotron motion of ions, having different mass/charge ratios, in a constant magnetic field is excited essentially simultaneously and coherently by a pulse or a radio-frequency electric field applied perpendicular to the magnetic field. The excited cyclotron motion of the ions is subsequently detected on so-called receiver plates as a time domain signal that contains all the cyclotron frequencies that have been excited. Fourier transformation of the time domain signal results in the frequency domain FT-ICR signal which, on the basis of the inverse proportionality between frequency and the mass/charge ratio, can be converted into a mass spectrum. The term is sometimes contracted to Fourier transform mass spectrometer (FT-MS). See also: ion cyclotron resonance (ICR) mass spectrometer Source: PAC, 1991, 63, 1541 (Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)) on page 1545 |
IUPAC Gold Book |
Index of Gold Book Terms |
Proteomics Standards Initiative Term |
Fourier transform-ion cyclotron resonance-mass spectrometer |
---|
A mass spectrometer based on the principle of ion cyclotron resonance in which an ion in a magnetic field moves in a circular orbit at a frequency characteristic of its m/z value. Ions are coherently excited to a larger radius orbit using a pulse of radio frequency energy and their image charge is detected on receiver plates as a time domain signal. Fourier transformation of the time domain signal results in a frequency domain signal which is converted to a mass spectrum based in the inverse relationship between frequency and m/z. [database_cross_reference: PSI:MS] |
Superclasses: mass analyzer type |
ID: MS:MS:1000079
Synonym: [[ {{{syn}}} ]] has_exact_synonym:FT_ICR |
Full list of terms | PSI Terms |