Kendrick mass: Difference between revisions

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{{Def|
Kendrick mass
|
def=Mass scale obtained by multiplying the [[atomic mass unit]] (u) (or equivalently the dalton (Da)) by the ratio of the mass of the CH<sub>2</sub> group to 14.0000 to simplify the display of peak patterns in hydrocarbon [[mass spectra]].
 
:Note: The scaling factor is 14.0156/14.000.
|ref=Kendrick, Edward (1963). "A mass scale based on CH2 = 14.0000 for high resolution mass spectrometry of organic compounds". Anal. Chem. 35: 2146-2154. Retrieved 2010-01-25.
 
Marshall AG, Rodgers RP (January 2004). "Petroleomics: the next grand challenge for chemical analysis". Acc. Chem. Res. 37 (1): 53-9. doi:10.1021/ar020177t. PMID 14730994.
|rel=[[mass defect]]
|acronym=
}}
{{defect}}

Latest revision as of 17:53, 12 June 2022

DRAFT DEFINITION
Kendrick mass
Mass scale obtained by multiplying the atomic mass unit (u) (or equivalently the dalton (Da)) by the ratio of the mass of the CH2 group to 14.0000 to simplify the display of peak patterns in hydrocarbon mass spectra.
Note: The scaling factor is 14.0156/14.000.
Related Term(s): mass defect
Reference(s):

Kendrick, Edward (1963). "A mass scale based on CH2 = 14.0000 for high resolution mass spectrometry of organic compounds". Anal. Chem. 35: 2146-2154. Retrieved 2010-01-25.

Marshall AG, Rodgers RP (January 2004). "Petroleomics: the next grand challenge for chemical analysis". Acc. Chem. Res. 37 (1): 53-9. doi:10.1021/ar020177t. PMID 14730994.

This is an unofficial draft definition presented for information and comment.

Recommended terms | Full list of terms

 

Mass defect

Mass defect in mass spectrometry and nuclear physics

Mass defect (mass spectrometry)
The difference between the exact mass and the nearest integer mass
Mass defect (physics)
The difference between the mass of a composite particle and the sum of the masses of its parts

Links

Land, A. Neutrons in the Nucleus. I. Phys. Rev. 43, 620-623 (1933).
http://dx.doi.org/10.1103/PhysRev.43.620
Carlson (1960); High Resolution Mass Spectrometry. Interpretation of Spectra of Petroleum Fractions
http://dx.doi.org/10.1021/ac60167a032
Kendrick (1963); A Mass Scale Based on CH2= 14.0000 for High Resolution Mass Spectrometry of Organic Compounds.
http://dx.doi.org/10.1021/ac60206a048
Hughey (2001); Kendrick Mass Defect Spectrum:? A Compact Visual Analysis for Ultrahigh-Resolution Broadband Mass Spectra
http://dx.doi.org/10.1021/ac010560w
Zhang (2003); A software filter to remove interference ions from drug metabolites in accurate mass liquid chromatography/mass spectrometric analyses
http://dx.doi.org/10.1002/jms.521
Hall, M.P., Ashrafi, S., Obegi, I., Petesch, R., Peterson, J.N., Schneider, L.V. Mass defect tags for biomolecular mass spectrometry. J. Mass Spectrom. 38, 809-816 (2003).
http://dx.doi.org/10.1002/jms.493
Zhang (2009); Mass defect filter technique and its applications to drug metabolite identification by high-resolution mass spectrometry
http://dx.doi.org/10.1002/jms.1610
Sleno (2012); The use of mass defect in modern mass spectrometry
http://dx.doi.org/10.1002/jms.2953
Pourshahian (2017); Mass Defect from Nuclear Physics to Mass Spectral Analysis
http://dx.doi.org/10.1007/s13361-017-1741-9