Nozzle-skimmer dissociation

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IUPAC RECOMMENDATIONS 2013
Nozzle-skimmer dissociation
nozzle-skimmer dissociation

in-source collision-induced dissociation

Collisionally activated dissociation that is caused by collisions in the region between the nozzle and skimmer of an atmospheric pressure ionization source such as electrospray or atmospheric pressure chemical ionization.

Note: The process can be induced by a higher than typical nozzle-skimmer voltage.
Related Term(s):
Reference(s):

M. W. Senko, S. C. Beu, F. W. McLafferty. Anal. Chem. 66, 415 (1994). (http://dx.doi.org/10.1021/ac00075a016 )

J. A. Loo, H. R. Udseth, R. D. Smith. Rapid Commun. Mass Spectrom. 2, 207 (1988). (http://dx.doi.org/10.1002/rcm.1290021006 )

From Definitions of Terms Relating to Mass Spectrometry (IUPAC Recommendations 2013); DOI: 10.1351/PAC-REC-06-04-06 © IUPAC 2013.

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