Principal ion: Difference between revisions
(→Orange Book entry: Orange Book cat case using AWB) |
No edit summary |
||
Line 8: | Line 8: | ||
{{orange| | {{orange| | ||
This is defined as a [[Molecular Ion|molecular]] or [[fragment ion]] which is made up of the most abundant isotopes of each of its atomic constituents. In the case of compounds that have been artificially enriched in one or more positions such as CH<sub>3</sub> <sup>13</sup>CH<sub>3</sub> or CH<sub>2</sub>D<sub>2</sub> the principal ion may be defined by treating the heavy isotopes as new atomic species. Thus in the two above example the principal ions would be of masses 13 and 18, respectively. | This is defined as a [[Molecular Ion|molecular]] or [[fragment ion]] which is made up of the most abundant isotopes of each of its atomic constituents. In the case of compounds that have been artificially enriched in one or more positions such as CH<sub>3</sub> <sup>13</sup>CH<sub>3</sub> or CH<sub>2</sub>D<sub>2</sub> the principal ion may be defined by treating the heavy isotopes as new atomic species. Thus in the two above example the principal ions would be of masses 13 and 18, respectively. | ||
}} | |||
== Gold Book entry == | |||
{{gold| | |||
http://goldbook.iupac.org/P04847.html | |||
A molecular or fragment ion which is made up of the most abundant isotopes of each of its atomic constituents. In the case of compounds that have been artifically isotopically enriched in one or more positions such as CH313CH3 or CH2D2 the principal ion may be defined by treating the heavy isotopes as new atomic species. Thus, in the above two examples, the principal ions would be of masses 31 and 18, respectively. | |||
'''Source''': | |||
PAC, 1991, 63, 1541 ([[Recommendations for nomenclature and symbolism for mass spectroscopy]] (including an appendix of terms used in vacuum technology). (Recommendations 1991)) on page 1550 | |||
}} | }} | ||
Revision as of 23:41, 16 July 2009
Obsolete Template
Orange Book entry
Orange Book
ORANGE BOOK DEFINITION
IUPAC. Analytical Division. Compendium of Analytical Nomenclature (the Orange Book). Definitive Rules, 1979 (see also Orange Book 2023) |
Principal ion |
---|
This is defined as a molecular or fragment ion which is made up of the most abundant isotopes of each of its atomic constituents. In the case of compounds that have been artificially enriched in one or more positions such as CH3 13CH3 or CH2D2 the principal ion may be defined by treating the heavy isotopes as new atomic species. Thus in the two above example the principal ions would be of masses 13 and 18, respectively. |
IUPAC 1997 Orange Book Chapter 12 |
Index of Orange Book Terms |
Gold Book entry
Gold Book
GOLD BOOK DEFINITION
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the Gold Book). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). |
Principal ion |
---|
http://goldbook.iupac.org/P04847.html A molecular or fragment ion which is made up of the most abundant isotopes of each of its atomic constituents. In the case of compounds that have been artifically isotopically enriched in one or more positions such as CH313CH3 or CH2D2 the principal ion may be defined by treating the heavy isotopes as new atomic species. Thus, in the above two examples, the principal ions would be of masses 31 and 18, respectively. Source: PAC, 1991, 63, 1541 (Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)) on page 1550 |
IUPAC Gold Book |
Index of Gold Book Terms |