Principal ion: Difference between revisions
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|def=Most abundant ion of an [[isotope cluster]]. | |||
:''Note 1'': An example is the <sup>11</sup>B<sup>79</sup>Br<sub>2</sub><sup>81</sup>Br<sup>+•</sup> ion of ''[[m/z]]'' 250 of the cluster of isotopolog molecular ions of BBr<sub>3</sub>. | |||
:''Note 2'': Principal ion has also been used to describe ions that have been artificially isotopically enriched in one or more positions such as <sup>13</sup>CH<sub>3</sub> or CH<sub>2</sub>D<sub>2</sub>, but those are best defined as [[isotopolog ion]]s. | |||
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This is defined as a [[Molecular Ion|molecular]] or [[fragment ion]] which is made up of the most abundant isotopes of each of its atomic constituents. In the case of compounds that have been artificially enriched in one or more positions such as CH<sub>3</sub> <sup>13</sup>CH<sub>3</sub> or CH<sub>2</sub>D<sub>2</sub> the principal ion may be defined by treating the heavy isotopes as new atomic species. Thus in the two above example the principal ions would be of masses 13 and 18, respectively. | |||
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http://goldbook.iupac.org/P04847.html | |||
A molecular or fragment ion which is made up of the most abundant isotopes of each of its atomic constituents. In the case of compounds that have been artifically isotopically enriched in one or more positions such as CH313CH3 or CH2D2 the principal ion may be defined by treating the heavy isotopes as new atomic species. Thus, in the above two examples, the principal ions would be of masses 31 and 18, respectively. | |||
'''Source''': | |||
PAC, 1991, 63, 1541 ([[Recommendations for nomenclature and symbolism for mass spectroscopy]] (including an appendix of terms used in vacuum technology). (Recommendations 1991)) on page 1550 | |||
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[[Category:Ions]] | [[Category:Ions]] | ||
[[Category:Orange Book term]] | |||
{{DEFAULTSORT:Principal Ion}} |
Revision as of 16:21, 17 April 2021
IUPAC RECOMMENDATIONS 2013 |
Principal ion |
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Most abundant ion of an isotope cluster.
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Related Term(s): |
Reference(s):
IUPAC. Analytical Division. Compendium of Analytical Nomenclature (the Orange Book). Definitive Rules, 1979. Compiled by J. Inczédy, T. Lengyel, A. M. Ure. Blackwell Scientific Publications, Oxford (1997). On-line corrected version: http://www.iupac.org /publications/analytical compendium (2000). IUPAC. Compendium of Chemical Terminology, 2nd ed. (the Gold Book). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. |
From Definitions of Terms Relating to Mass Spectrometry (IUPAC Recommendations 2013); DOI: 10.1351/PAC-REC-06-04-06 © IUPAC 2013. |
Orange Book
ORANGE BOOK DEFINITION
IUPAC. Analytical Division. Compendium of Analytical Nomenclature (the Orange Book). Definitive Rules, 1979 (see also Orange Book 2023) |
Principal ion |
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This is defined as a molecular or fragment ion which is made up of the most abundant isotopes of each of its atomic constituents. In the case of compounds that have been artificially enriched in one or more positions such as CH3 13CH3 or CH2D2 the principal ion may be defined by treating the heavy isotopes as new atomic species. Thus in the two above example the principal ions would be of masses 13 and 18, respectively. |
IUPAC 1997 Orange Book Chapter 12 |
Index of Orange Book Terms |
Gold Book
GOLD BOOK DEFINITION
IUPAC. Compendium of Chemical Terminology, 2nd ed. (the Gold Book). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). |
Principal ion |
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http://goldbook.iupac.org/P04847.html A molecular or fragment ion which is made up of the most abundant isotopes of each of its atomic constituents. In the case of compounds that have been artifically isotopically enriched in one or more positions such as CH313CH3 or CH2D2 the principal ion may be defined by treating the heavy isotopes as new atomic species. Thus, in the above two examples, the principal ions would be of masses 31 and 18, respectively. Source: PAC, 1991, 63, 1541 (Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)) on page 1550 |
IUPAC Gold Book |
Index of Gold Book Terms |