Difference between revisions of "Unimolecular dissociation"
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Fragmentation in which the molecularity
Fragmentation in which the molecularity of the from [[metastable ion]] or [[collisional excitation]]
Latest revision as of 19:42, 8 January 2014
|IUPAC RECOMMENDATIONS 2013|
|Fragmentation reaction in which the molecularity of the reaction system is unity. The dissociation may arise from the extra energy acquired by a metastable ion produced in the ion source or that provided by collisional excitation of a stable ion.|
P. J. Robinson, K. A. Holbrook. Unimolecular Reactions, John Wiley, New York (1972).
|From Definitions of Terms Relating to Mass Spectrometry (IUPAC Recommendations 2013); DOI: 10.1351/PAC-REC-06-04-06 © IUPAC 2013.|